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Jamb 2018 Chemistry Syllabus and Recommended textbooks - solutionfans.com
   

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    The aim of this 2018/2019 Unified Tertiary Matriculation Examination (UTME) syllabus in Chemistry is to prepare the candidates for the Board’s examination. It is designed to test their achievement of the course objectives, which are to:

    (i) understand the basic principles and concepts in chemistry;

    (ii) interpret scientific data relating to chemistry

    (iii) deduce the relationships between chemistry and other sciences;

    (iv) apply the knowledge of chemistry to industry and everyday life.

    TOPICS/CONTENTS/NOTES OBJECTIVES

    1. Separation of mixtures and purification of chemical substances

    (a) Pure and impure substances

    (b) Boiling and melting points.

    (c) Elements, compounds and mixtures

    (d) Chemical and physical changes.

    (e) Separation processes:

    evaporation, simple and fractional distillation, sublimation, filtration, crystallization, paper and column chromatography, simple and fractional crystallization, magnetization, decantation. Candidates should be able to:

    (i) distinguish between pure and impure substances;

    (ii) use boiling and melting points as criteria for purity of chemical substances;

    (iii) distinguish between elements, compounds and mixture;

    (iv) differentiate between chemical and physical changes;

    (v) identify the properties of the components of a mixture;

    (vi) specify the principle involved in each separation method.

    (vii) apply the basic principle of separation processes in everyday life.

    2. Chemical combination

    Stoichiometry, laws of definite and multiple proportions, law of conservation of matter, Gay Lussac’s law of combining volumes, Avogadro’s law; chemical symbols, formulae, equations and their uses, relative atomic mass

    based on C=12, the mole concept and Avogadro’s number. Candidates should be able to:

    (i) perform simple calculations involving formulae, equations/chemical composition and the mole concept;

    (ii) deduce the chemical laws from given expressions/statements/data;

    (iii) interpret graphical representations related

    to these laws;

    (iv) deduce the stoichiometry of chemical reactions.

    3. Kinetic theory of matter and Gas Laws

    (a) An outline of the kinetic theory of matter;

    (i) melting,

    (ii) vapourization

    (iii) boiling

    (iv) freezing

    (v) condensation

    in terms of molecular motion and Brownian movement.

    (b)(i) The laws of Boyle, Charles, Graham and Dalton (law of partial pressure); combined gas law, molar volume and atomicity of gases.

    (ii) The ideal gas equation (PV = nRT).

    (iii) The relationship between vapour density of gases and the relative molecular mass. Candidates should be able to:

    (i) apply the theory to distinguish between solids, liquids and gases;

    (ii) deduce reasons for change of state;

    (iii) draw inferences based on molecular motion;

    (iv) deduce gas laws from given expressions/ statements;

    (v) interpret graphical representations related to these laws;

    (vi) perform simple calculations based on these laws, equations and relationships

    4. Atomic structure and bonding

    (a) (i)The concept of atoms, molecules and ions, the works of Dalton, Millikan, Rutherford, Moseley, Thompson and Bohr.

    (ii) Atomic structure, electron configuration, atomic number, mass number and isotopes; specific examples should be drawn from elements of atomic number 1 to 20.

    (iii) Shapes of s and p orbitals.

    (b) The periodic table and periodicity of elements, presentation of the periodic table with a view to recognizing families of elements e.g. alkali metals, halogens, the noble gases and transition metals. The variation of the following properties: ionization energy, ionic radii, electron affinity and electronegativity.

    (c) Chemical bonding.

    Electrovalency and covalency, the electron configuration of elements and their tendency to attain the noble gas structure. Hydrogen bonding and metallic bonding as special types of electrovalency and covalency respectively; coordinate bond as a type of covalent bond as illustrated by complexes like [Fe(CN) ] , [Fe(CN) ] , [Cu(NH ) ] and [Ag(NH ) ] ; van der Waals’ forces should be mentioned as a special type of bonding forces.

    (d) Shapes of simple molecules: linear ((H , O , C ,HCl and CO ), non-linear (H O) and tetrahedral; (CH ) and pyramidal (NH ).

    (e) Nuclear Chemistry:

    (i) Radioactivity – Types and properties of

    radiations

    (ii) Nuclear reactions. Simple equations,

    uses and applications of natural and

    artificial radioactivity. Candidates should be able to:

    (i) distinguish between atoms, molecules and ions;

    (ii) identify the contributions of these scientists to

    the development of the atomic structure;

    (iii) deduce the number of protons, neutrons and

    electrons from atomic and mass numbers of

    an atom;

    (iv) apply the rules guiding the arrangement of

    electrons in an atom;

    (v) identity common elements exhibiting isotopy;

    (vi) relate isotopy to mass number;

    (vii) perform simple calculations relating to isotopy;

    (viii) differentiate between the shapes of the orbitals;

    (ix) determine the number of electrons in s and

    p atomic orbitals;

    (x) relate atomic number to the position of an

    element on the periodic table;

    (xi) relate properties of groups of elements on the periodic table;

    (xii) identify reasons for variation in properties

    across the period and down the groups.

    (xiii) differentiate between the different types

    of bonding.

    (xiv) deduce bond types based on electron

    configurations;

    (xv) relate the nature of bonding to properties

    of compounds;

    (xvi) differentiate between the various shapes

    of molecules

    xvii) distinguish between ordinary chemical

    reaction and nuclear reaction;

    (xviii) differentiate between natural and

    artificial radioactivity;

    (xix) compare the properties of the different

    types of nuclear radiations;

    (xx) compute simple calculations on the

    half-life of a radioactive material;

    (xxi) balance simple nuclear equation;

    (xxii) identify the various applications of

    radioactivity.

    5. Air

    (a) The natural gaseous constituents and their proportion in the air.

    – nitrogen, oxygen, water vapour, carbon (IV) oxide and the noble gases (argon and neon).

    (b) Air as a mixture and some uses of the noble gas. Candidates should be able to:

    (i) deduce reason (s) for the existence of

    air as a mixture;

    (ii) identify the principle involved in the

    separation of air components;

    (iii) deduce reasons for the variation in the

    composition of air in the environment;

    (iv) specify the uses of some of the

    constituents of air.

    6. Water

    (a) Water as a product of the combustion of hydrogen and its composition by volume.

    (b) Water as a solvent, atmospheric gases dissolved in water and their biological significance.

    (c) Hard and soft water:

    Temporary and permanent

    hardness and methods of softening

    hard water.

    (d) Treatment of water for town supply.

    (e) Water of crystallization, efflorescence,

    deliquescence and hygroscopy. Examples of the substances exhibiting these properties and their uses. Candidates should be able to:

    (i) identify the various uses of water;

    (ii) identity the effects of dissolved atmospheric

    gases in water;

    (iii) distinguish between the properties of hard and

    soft water;

    (iv) determine the causes of hardness;

    (v) identify methods of removal of hardness;

    (vi) describe the processes involved in the

    treatment of water for town supply;

    (vii) distinguish between these phenomena;

    (viii) identify the various compounds that exhibit

    these phenomena.

    7. Solubility

    (a) Unsaturated, saturated and supersaturated solutions. Solubility curves and simple deductions from them, (solubility defined in terms of mole per dm ) and simple calculations.

    (b) Solvents for fats, oil and paints

    and the use of such solvents

    for the removal of stains.

    (c) False solution (Suspensions and colloids):

    Properties and examples.

    Harmattan haze and water paints as examples

    of suspensions and fog, milk, aerosol spray,

    emulsion paints and rubber solution as

    examples of colloids. Candidates should be able to:

    (i) distinguish between the different types of

    solutions;

    (ii) interpret solubility curves;

    (iii) calculate the amount of solute that can

    dissolve in a given amount of solvent at a

    given temperature;

    (iv) deduce that solubility is temperature-dependent;

    (v) relate nature of solvents to their uses;

    (vi) differentiate among true solution,

    suspension and colloids;

    (vii) compare the properties of a true solution

    and a �false’ solution.

    (viii) provide typical examples of suspensions

    and colloids.

    8. Environmental Pollution

    (a) Sources and effects of pollutants.

    (b) Air pollution:

    Examples of air pollutants such as

    H S, CO, SO , oxides of nitrogen,

    chlorofluorocarbons and dust.

    (c) Water pollution

    Sewage and oil pollution should be

    known.

    (d) Soil pollution:

    Oil spillage, Biodegradable and

    non-biodegradable pollutants. Candidates should be able to:

    (i) identify the different types of pollution and

    pollutants;

    (ii) specify different sources of pollutants

    (iii) classify pollutants as biodegradable and

    non-biodegradable;

    (iv) specify the effects of pollution on the

    environment;

    (v) identify measures for control of

    environmental pollution.

    9. Acids, bases and salts

    (a) General characteristics and properties of acids, bases and salts. Acids/base indicators, basicity of acids; normal, acidic, basic and

    double salts. An acid defined as a substance whose aqueous solution furnishes H3O ions or as a proton donor. Ethanoic, citric and tartaric acids as examples of naturally occurring organic acids, alums as examples

    of double salts, preparation of salts by neutralization, precipitation and action of acids on metals. Oxides and trioxocarbonate (IV) salts

    (b) Qualitative comparison of the

    conductances of molar solutions of

    strong and weak acids and bases,

    relationship between conductance and

    amount of ions present.

    (c) pH and pOH scale; Simple calculations

    (d) Acid/base titrations.

    (e) Hydrolysis of salts: Principle

    Simple examples such as

    NH Cl, AlCl , Na CO and CH COONa Candidates should be able to:

    (i) distinguish between the properties of

    acids and bases;

    (ii) identify the different types of acids

    and bases;

    (iii) determine the basicity of acids;

    (iv) differentiate between acidity and

    alkalinity using acid/base indicators;

    (v) identify the various methods of

    preparation of salts;

    (vi) classify different types of salts;

    (vii) relate degree of dissociation to strength

    of acids and bases;

    (viii) relate degree of dissociation to

    conductance;

    (ix) perform simple calculations on pH and pOH;

    (x) identify the appropriate acid-base

    indicator;

    (xi) interpret graphical representation of

    titration curves;

    (xii) perform simple calculations based on

    the mole concept;

    (xiii) balance equations for the hydrolysis

    of salts;

    (xiv) deduce the properties (acidic, basic,

    neutral) of the resultant solution.

    10. Oxidation and reduction

    (a) Oxidation in terms of the addition of oxygen or removal of hydrogen.

    (b) Reduction as removal of oxygen or

    addition of hydrogen.

    (c) Oxidation and reduction in terms of electron transfer.

    (d) Use of oxidation numbers. Oxidation and reduction treated as change in oxidation number and use of oxidation numbers in balancing simple equations.

    (e) IUPAC nomenclature of inorganic compounds using oxidation number.

    (f) Tests for oxidizing and reducing agents. Candidates should be able to:

    (i) identify the various forms of expressing

    oxidation and reduction;

    (ii) classify chemical reactions in terms of

    oxidation or reduction;

    (iii) balance redox reaction equations;

    (iv) deduce the oxidation number of chemical

    species;

    (v) compute the number of electron transfer

    in redox reactions;

    (vi) identify the name of redox species in a reaction

    (vii) distinguish between oxidizing and reducing

    agents in redox reactions.

    (viii) apply oxidation number in naming inorganic compounds

    (ix) relate reagents to their oxidizing and reducing abilities.

    11. Electrolysis

    (a) Electrolytes and non-electrolytes.

    Faraday’s laws of electrolysis.

    (b) (i) Electrolysis of dilute H SO4, aqueous

    CuSO , CuC solution, dilute and concentrated NaC1 solutions and fused NaC1

    (ii) Factors affecting discharge of ions at the electrodes.

    (c) Uses of electrolysis:

    Purification of metals e.g. copper and

    production of elements and compounds

    (Al, Na, O , C and NaOH).

    (d) Electrochemical cells:

    Redox series (K, Ca, Na, Mg, Al, Zn, Fe, Sn, Pb, H, Cu, Hg, Ag, Au,)

    half-cell reactions and electrode potentials. (Simple calculations only).

    (e) Corrosion as an electrolytic process,

    cathodic protection of metals,

    painting, electroplating and coating

    with grease or oil as ways of

    preventing iron from corrosion. Candidates should be able to:

    (i) distinguish between electrolytes and non-

    electrolytes;

    (ii) perform calculations based on faraday as a

    mole of electrons.

    (iii) identify suitable electrodes for different

    electrolytes.

    (iv) specify the chemical reactions at the

    electrodes;

    (v) determine the products at the electrodes;

    (vi) identify the factors that affect the products

    of electrolysis;

    (vii) specify the different areas of application of

    electrolysis;

    (viii) identify the various electrochemical cells;

    (ix) calculate electrode potentials using half-

    cell reaction equations;

    (x) determine the different areas of

    application of electrolytic processes;

    (xi) identify methods used in protecting metals.

    12. Energy changes

    (a) Energy changes( Δ H) accompanying physical

    and chemical changes:

    dissolution of substances in/or

    reaction with water e.g. Na, NaOH,

    K, NH Cl. Endothermic (+ Δ H) and exothermic (- Δ H) reactions.

    (b) Entropy as an order-disorder

    phenomenon: simple illustrations

    like mixing of gases and dissolution

    of salts.

    (c) Spontaneity of reactions:

    Δ G θ = 0 as a criterion for equilibrium, Δ G

    greater or less than zero as a criterion for

    non-spontaneity or spontaneity respectively. Candidates should be able to:

    (i) determine the types of heat changes

    ( Δ H) in physical and chemical processes;

    (ii) interpret graphical representations of heat

    changes;

    (iii) relate the physical state of a substance

    to the degree of orderliness;

    (iv) determine the conditions for spontaneity

    of a reaction ;

    (v) relate Δ H θ, Δ S θ and

    Δ G θ as the driving

    forces for chemical reactions;

    (vi) solve simple problems based on the

    relationships Δ G θ= Δ H θ -T Δ Sθ

    13. Rates of Chemical Reaction

    (a) Elementary treatment of the following factors which can change the rate of a chemical reaction:

    (i) Temperature e.g. the reaction between HCl and Na S O or Mg and HCl

    (ii) Concentration e.g. the reaction between HCl and Na S O , HCl and marble and the iodine clock reaction, for gaseous systems, pressure may be used as concentration term.

    (iii) Surface area e.g. the reaction

    between marble and HCl with

    marble in

    (i) powdered form

    (ii) lumps of the same mass.

    (iv) Catalyst e.g. the decomposition

    of H O or KClO in the

    presence or absence of MnO

    (b) Reaction rate curves.

    (c) Activation energy

    Qualitative treatment of Arrhenius’ law and

    the collision theory, effect of light on some

    reactions. e.g. halogenation of alkanes Candidates should be able to:

    (i) identify the factors that affect the rates of a chemical reaction;

    (ii) determine the effects of temperature on

    the rate of reactions;

    (iii) examine the effect of concentration/pressure on

    the rate of a chemical reaction;

    (iv) describe how the rate of a chemical reaction is

    affected by surface area;

    (v) determine the types of catalysts suitable for different reactions and their effects;

    (vi) determine ways of moderating these effects in chemical reactions.

    (vii) interpret reaction rate curves;

    (viii) solve simple problems on the rate of reactions;

    (ix) relate the rate of reaction to the kinetic theory of matter.

    (x) examine the significance of activation energy to chemical reactions.

    (xi) deduce the value of activation energy (Ea) from reaction rate curves.

    14. Chemical equilibra

    Reversible reactions and factors governing

    the equilibrium position. Dynamic

    equilibrium. Le Chatelier’s principle and equilibrium constant. Simple examples to

    include action of steam on iron and N O 2NO .

    No calculation will be required. Candidates should be able to:

    (i) identify the factors that affects the position

    of equilibrium of a chemical reaction;

    (ii) predict the effects of each factor on the position

    of equilibrium;

    (iii) determine the effects of these factors on

    equilibrium constant.

    15. Non-metals and their compounds

    (a) Hydrogen: commercial production from

    water gas and cracking of petroleum

    fractions, laboratory preparation,

    properties, uses and test for hydrogen.

    (b) Halogens: Chlorine as a representative

    element of the halogen. Laboratory preparation, industrial preparation by electrolysis, properties and uses, e.g. water sterilization, bleaching, manufacture of HCl, plastics and insecticides.

    Hydrogen chloride and Hydrochloric acid: Preparation and properties. Chlorides and test for chlorides.

    (c) Oxygen and Sulphur

    (i) Oxygen:

    Laboratory preparation, properties and uses. Commercial production from liquid air. Oxides: Acidic,basic, amphoteric and neutral, trioxygen (ozone) as an allotrope and the importance of ozone in the atmosphere.

    (ii) Sulphur:

    Uses and allotropes:

    preparation of allotropes is not expected . Preparation, properties and uses of sulphur(IV) oxide, the reaction of SO with alkalis. Trioxosulphate (IV) acid and its salts, the effect of acids on salts of trioxosulphate(IV), Tetraoxosulphate(VI) acid: Commercial preparation (contact process only), properties as a dilute acid, an oxidizing and a dehydrating agent and uses. Test for SO .

    Hydrogen sulphide: Preparation and properties as a weak acid, reducing agent and precipitating agent. Test for S

    (d) Nitrogen:

    (i) Laboratory preparation

    (ii) Production from liquid air

    (iii) Ammonia:

    Laboratory and industrial

    preparations (Haber Process only),

    properties and uses, ammonium salts

    and their uses, oxidation of

    ammonia to nitrogen (IV)

    oxide and trioxonitrate (V)

    acid.

    Test for NH

    (iv) Trioxonitrate (V) acid:

    Laboratory preparation

    from ammonia;

    properties and uses. Trioxonitrate (V) salt-

    action of heat and uses. Test for NO

    (v) Oxides of nitrogen:

    Properties.

    The nitrogen cycle.

    (e) Carbon:

    (i) Allotropes: Uses and

    properties

    (ii) Carbon(IV) oxide-

    Laboratory preparation, properties

    and uses. Action of heat on

    trioxocarbonate (IV) salts and test for

    CO

    (iii) Carbon(II) oxide:

    Laboratory preparation, properties

    including its effect on blood;

    sources of carbon (II) oxide to

    include charcoal, fire and exhaust

    fumes.

    (iv) Coal: Different types, products

    obtained from destructive

    distillation of wood and coal.

    (v) Coke: Gasification and uses.

    Manufacture of synthetic gas and

    uses. Candidates should be able to:

    (i) predict reagents for the laboratory and

    industrial preparation of these gases and

    their compounds.

    (ii) identify the properties of the gases and their

    compounds.

    (iii) compare the properties of these gases and

    their compounds.

    (iv) specify the uses of each gas and its

    compounds;

    (v) determine the specific test for each gas and its

    compounds.

    (vi) determine specific tests for Cl , SO , SO ,

    S , NH , NO , CO , HCO

    (vii) predict the reagents for preparation,

    properties and uses HCl(g) and HCl(aq);

    (viii) identify the allotropes of oxygen;

    (ix) determine the significance of ozone to

    our environment.

    (x) classify the oxides of oxygen and their

    properties

    (xi) identify the allotropes of sulphur and their

    uses;

    (xii) predict the reagents for preparation, properties

    and uses of SO and H S;

    (xiii) specify the preparations of H SO and H SO ,

    their properties and uses.

    (xiv) specify the laboratory and industrial

    preparation of NH ;

    (xv) identify the properties and uses of NH ;

    (xvi) identify reagents for the laboratory

    preparation of HNO , its properties and

    uses;

    (xvii) specify the properties of N O, NO, NO gases.

    (xviii) examine the relevance of nitrogen cycle

    to the environment.

    (xix) identify allotropes of carbon;

    (xx) predict reagents for the laboratory

    preparation of CO ;

    (xxi) specify the properties of CO and its

    uses;

    (xxii) determine the reagents for the

    laboratory preparation of CO;

    (xxiii) predict the effects of CO on human;

    (xxiv) identify the different forms of coal:

    (xxv) determine their uses;

    (xxvi) specify the products of the destructive distillation of wood and coal;

    (xxvii) specify the uses of coke and synthetic gas.

    16. Metals and their compounds

    (a) General properties of metals

    (b) Alkali metals e.g. sodium

    (i) Sodium hydroxide:-

    Production by electrolysis of

    brine, its action on aluminium, zinc and lead ions.

    Uses including precipitation of

    metallic hydroxides.

    (ii) Sodium trioxocarbonate (IV)

    and sodium hydrogen trioxocarbonate (IV): Production by Solvay process, properties and uses, e.g.

    Na CO in the manufacture of glass.

    (iii) Sodium chloride: its occurrence in

    sea water and uses, the economic

    importance of sea water and the

    recovery of sodium chloride.

    (c) Alkaline-earth metals, e.g. calcium;

    calcium oxide, calcium hydroxide

    and calcium trioxocarbonate (IV);

    Properties and uses. Preparation of calcium oxide from sea shells, the

    chemical composition of cement

    and the setting of mortar. Test for Ca .

    (d) Aluminium

    Purification of bauxite, electrolytic

    extraction, properties and uses of aluminium and its compounds. Test for A1

    (e) Tin

    Extraction from its ores.

    Properties and uses.

    (f) Metals of the first transition series.

    Characteristic properties:

    (i) electron configuration

    (ii) oxidation states

    (iii) complex ion formation

    (iv) formation of coloured ions

    (v) catalysis

    (g) Iron

    Extraction from sulphide and oxide

    ores, properties and uses, different forms

    of iron and their properties and

    advantages of steel over iron.

    Test for Fe and Fe

    (h) Copper

    Extraction from sulphide and oxide

    ores, properties and uses of copper.

    Preparation and uses of copper( II )

    tetraoxosulphate(VI). Test for Cu

    (i) Alloy

    Steel, stainless steel, brass, bronze, type- metal, duralumin, soft solder,

    permallory and alnico (constituents and

    uses only). Candidates should be able to:

    (i) specify the general properties of metals;

    (ii) determine the method of extraction suitable

    for each metal;

    (iii) relate the methods of extraction to the

    properties for the metals;

    (iv) compare the chemical reactivities of the metals;

    (v) specify the uses of the metals;

    (vi) determine specific test for metallic ions;

    (vii) determine the process for the production

    of the compounds of these metals;

    (viii) compare the chemical reactivities of the

    compounds;

    (ix) specify the uses of these compounds;

    (x) specify the chemical composition of cement.

    (xi) describe the method of purification of bauxite;

    (xii) specify the ores of tin;

    (xiii) relate the method of extraction to its properties;

    (xiv) specify the uses of tin;

    (xv) identify the general properties of the first

    transition metals;

    (xvi) deduce reasons for the specific properties

    of the transition metals;

    (xvii) determine the IUPAC names of simple

    transition metal complexes

    (xviii) determine the suitable method of

    extraction of iron;

    (xix) specify the properties and uses of iron;

    (xx) identify the different forms of iron, their compositions, properties and uses.

    (xxi) identify the appropriate method of

    extraction of copper from its compounds;

    (xxii) relate the properties of copper and its

    compound to their uses.

    (xxiii) specify the method for the preparation of

    CuSO ;

    (xxiv) specify the constituents and uses of the

    various alloys mentioned.

    (xxv) compare the properties and uses of alloys

    to pure metals.

    17. Organic Compounds

    An introduction to the tetravalency of

    carbon, the general formula, IUPAC

    nomenclature and the determination of

    empirical formula of each class of the

    organic compounds mentioned below.

    (a) Aliphatic hydrocarbons

    (i) Alkanes

    Homologous series in relation

    to physical properties,

    substitution reaction and a few

    examples and uses of halogenated

    products. Isomerism: structural

    only (examples on isomerism should

    not go beyond six carbon atoms).

    Petroleum: composition, fractional distillation and major products; cracking and reforming, Petrochemicals – starting materials of organic syntheses, quality of petrol and meaning of octane number.

    (ii) Alkenes

    Isomerism: structural and geometric

    isomerism, additional and

    polymerization reactions, polythene

    and synthetic rubber as examples of

    products of polymerization and its use

    in vulcanization.

    (iii) Alkynes

    Ethyne – production from action of

    water on carbides, simple reactions and

    properties of ethyne.

    (b) Aromatic hydrocarbons e.g. benzene –

    structure, properties and uses.

    (c) Alkanols

    Primary, secondary, tertiary – production

    of ethanol by fermentation and from

    petroleum by-products. Local examples

    of fermentation and distillation, e.g.

    gin from palm wine and other local

    sources and glycerol as a polyhydric

    alkanol.

    Reactions of OH group – oxidation as a distinguishing test among primary, secondary

    and tertiary alkanols (Lucas test).

    (d) Alkanals and alkanones.

    Chemical test to distinguish between

    alkanals and alkanones.

    (e) Alkanoic acids.

    Chemical reactions; neutralization and

    esterification, ethanedioic (oxalic) acid

    as an example of a dicarboxylic acid

    and benzene carboxylic acid as an

    example of an aromatic acid.

    (f) Alkanoates

    Formation from alkanoic acids and

    alkanols – fats and oils as alkanoates.

    Saponification:

    Production of soap and margarine from

    alkanoates and distinction between

    detergents and soaps.

    (g) Amines (Alkanamines) Primary, Secondary,

    and tertiary

    (h) Carbohydrates

    Classification – mono-, di- and polysaccharides; composition, chemical tests for simple sugars and reaction with concentrated tetraoxosulphate (VI) acid. Hydrolysis of complex sugars e.g. cellulose from cotton and starch from cassava, the uses of sugar and starch in the production of alcoholic beverages, pharmaceuticals and textiles.

    (i) Proteins:

    Primary structures, hydrolysis and tests (Ninhydrin, Biuret, Millon’s and xanthoproteic)

    Enzymes and their functions.

    (j) Polymers:

    Natural and synthetic rubber; addition and condensation polymerization.

    – Methods of preparation, examples and uses.

    Thermoplastic and thermosetting plastics. Candidates should be able to:

    (i) derive the name of organic compounds from

    their general formulae;

    (ii) relate the name of a compound to its structure

    (iii) relate the tetravalency of carbon to its ability

    to form chains of compound (catenation);

    (iv) classify compounds according to their

    functional groups;

    (v) derive empirical formula and molecular

    formula, from given data;

    (vi) relate structure/functional groups to specific

    properties;

    (vii) derive various isomeric forms from a given

    formula;

    (viii) distinguish between the different types of

    isomerism;

    (ix) classify the various types of hydrocarbons;

    (x) distinguish each class of hydrocarbons by their properties;

    (xi) specify the uses of various hydrocarbons;

    (xii) identify crude oil as a complex mixture

    of hydrocarbons;

    (xiii) relate the fractions of hydrocarbons to their

    properties and uses;

    (xiv) relate transformation processes to quality

    improvement of the fractions;

    (xv) distinguish between various polymerization

    processes;

    (xvi) specify the process involved in vulcanization;

    (xvii) specify chemical test for terminal alkynes

    (xviii) distinguish between aliphatic and aromatic

    hydrocarbons;

    (xix) relate the properties of benzene to its structure

    (xx) compare the various classes of alkanols;

    (xxi) determine the processes involved in ethanol

    production;

    (xxii) examine the importance of ethanol as an

    alternative energy provider;

    (xxiii) distinguish the various classes of alkanols;

    (xxiv) differentiate between alkanals and alkanones;

    (xxv) compare the various types of alkanoic acids;

    (xxvi) identify natural sources of alkanoates;

    (xxvii) specify the methods for the production of

    soap, detergent and margarine.

    (xxviii) distinguish between detergent and soap;

    (xxix) compare the various classes of alkanamine;

    (xxx) identify the natural sources of

    carbohydrates;

    (xxxi) compare the various classes of

    carbohydrates;

    (xxxii) infer the products of hydrolysis and

    dehydration of carbohydrates;

    (xxxiii) determine the uses of carbohydrates;

    (xxxiv) specify the tests for simple sugars;

    (xxxv) identify the basic structure of proteins;

    (xxxvi) specify the methods and products of

    hydrolysis;

    (xxxvii) specify the various tests for proteins;

    (xxxviii) distinguish between natural and synthetic

    polymers;

    (xxxix) differentiate between addition and

    condensation polymerization processes;

    (xl) classify natural and commercial polymers

    and their uses;

    (xli) distinguish between thermoplastics and

    thermosetting plastics.

    18. Chemistry and Industry

    Chemical industries: Types, raw materials and

    relevancies; Biotechnology. Candidates should be able to :

    (i) classify chemical industries interms of products;

    (ii) identify raw materials for each industry;

    (iii) distinguish between fine and heavy

    chemicals;

    (iv) enumerate the relevance of each of these

    industries;

    (v) relate industrial processes to biotechnology.

    ________________________________________________

    RECOMMENDED TEXTS

    1. New School Chemistry for Senior Secondary Schools, Ababio, O. Y. (2009), (Fourth edition), Onitsha: Africana FIRST Publishers Limited.

    2. Senior Secondary Chemistry, Bajah, S.T.; Teibo, B. O., Onwu, G.; and Obikwere, A. Book 1 (1999), Books 2 and 3 (2000). Lagos: Longman.

    3. Understanding Chemistry for Schools and Colleges, Ojokuku, G. O. (2012, Revised Edition), Zaria: Press-On Chemresources.

    4. Essential: Chemistry for Senior Secondary Schools, (2008), 2nd Edition, I. A. Odesina, Lagos: Tonad Publishers Limited.

    5. Countdown to WASSCE/SSCE, NECO, JME Chemistry, Uche, I. O.; Adenuga, I. J. and Iwuagwu, S. L. (2003). Ibadan: Evans.



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    Master Solution November 22, 2017 Categories: JAMB 589


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