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    NECO – CHEMISTRY – PRACTICALS – ANSWER
    1 ai)
    Tabulate
    Titrations| Rough | first ( 1 )|second ( 2 )|third ( 3 )
    Final burette reading – | 20. 50| 14. 90| 15. 00| 15. 10|
    initial burette reading – | 0 . 00| 0 . 00| 0 . 00| 0 . 00|
    volume of Acide used – | 20. 5 | 14. 90| 15. 00| 15. 10|
    1 ai)
    average volume of Acid used
    1 st + 2 nd + 3 rd / 3
    14. 90+ 15. 00+ 15. 10/ 3 = 45/ 3 = 15cm^ 3
    1 aii )
    2 HCL ( aq ) + Na 2 CO 3 ( aq ) – – – – > 2 NaCl ( aq ) + H 2 O( aq ) + CO 2 ( aq )
    1 bi)
    CA VA / CB VB = NA / NB
    0 . 1 moldm ^ – 3 * 15cm^ 3 / CB * 25cm^ 3 * 2 / 1
    CB * 25cm^ 3 * 2 = 0 . 1 moldm ^ – 3 * 15cm^ 3 * 1
    CB * 50= 1 . 5
    CB = 1 . 5 / 50= 0 . 03moldm ^ – 3
    1 bii )
    25cm^ 3 – – – – > 0 . 03mole
    1000cm^ 3 – – – – > x
    x= 1000* 0 . 03/ 25= 30/ 25
    x= 1 . 2 moldm ^ – 3
    1 biii)
    mold ^ – 3 = Con glm ^ 3 / molar mass
    0 . 03moldm ^ – 3 = x/ 106
    x= 0 . 03* 106
    x= 3 . 18gldm ^ 3
    ================================
    2 a )
    Tabulate
    2 ai)
    – OBSERVATION-
    i ) C dissolves in water
    ii) formation of white precipitate
    iii ) White precipitate dissolves in itel
    – INFERENCE –
    i ) C is soluble in water
    ii) CO 3 ^ – 2 ,SO4 ^ – 2 ,SO3 ^ 2 – suspected
    iii ) CO 3 ^ 2 – ,SO3 ^ 2 – , suspected
    2 bi)
    – OBERSVATION-
    i ) effervescence occurs with the evolution of a gas
    ii) the solutions turns to pink
    – INFERENCE –
    i ) CO 3 ^ 2 – ,SO3 ^ 2 – , suspected
    ii) CO 3 ^ 2 – ,Confrimed
    ================================
    3 ai)
    Zinc chloride reaction with HaOH form white gelatinous precipitate solution in excess HaOH.
    Ammonium trioxocarbonate ( iv ) on reaction with HaoH evolves a gas which turns red litmus paper blue and lime water milky .
    Calcium trioxocarbonate ( iv ) on reaction with HaoH forms white powdery precipitate insoluble in excess HaOH.
    3 aii )
    i ) liquid substance – – > crystallization
    ii) Solid substance – – > precipitation
    3 bi)
    i ) Evaporation takes place at all temperatures , while boiling occurs at a particular temperatur ( at boiling point ) .
    ii) Evaporation takes place from the surface , whereas the entire liquid boils .
    3 bii )
    Carbon ( iv ) oxide does not support combustion
    3 ci )
    molar solution is an aqueous solution that contains 1 mole ( gram – molecular weight ) of solute in 1 liter of the solution.
    3 cii )
    Indicator
    3 ciii )
    i ) methyl orange
    ii) Phenolphthalein .
    ================================
    Completed
    ===============================



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    Master Solution June 5, 2018 Categories: NECO 752


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